岩体三维节点偶对分析及其应用          下载免费PDF全文

王思敬  张菊明 《地质科学》1991,(3):277-287

本文讨论了节点偶对分析的三维扩展。节点偶对分析是针对摩擦滑动节理单元的约束边界进行的序列矢量判定。在三维节理单元的分析中,几何约束和相应的力学判据极为复杂,采用节点偶对等效结合力方法才能迎刃而解。文中对三维转向节理模型的分析得到合理的结果,它表明本文所提出的方法可成功地应用于节理岩体的有限元分析。  相似文献   

The geochemistry of gem opals as evidence of their origin     

Eloïse Gaillou  Aurlien Delaunay  Benjamin Rondeau  Martine Bouhnik-le-Coz  Emmanuel Fritsch  Guy Cornen  Christophe Monnier 《Ore Geology Reviews》2008,34(1-2):113

Seventy-seven gem opals from ten countries were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) through a dilution process, in order to establish the nature of the impurities. The results are correlated to the mode of formation and physical properties and are instrumental in establishing the geographical origin of a gem opal. The geochemistry of an opal is shown to be dependant mostly on the host rock, at least for examples from Mexico and Brazil, even if modified by weathering processes. In order of decreasing concentration, the main impurities present are Al, Ca, Fe, K, Na, and Mg (more than 500 ppm). Other noticeable elements in lesser amounts are Ba, followed by Zr, Sr, Rb, U, and Pb. For the first time, geochemistry helps to discriminate some varieties of opals. The Ba content, as well as the chondrite-normalized REE pattern, are the keys to separating sedimentary opals (Ba > 110 ppm, Eu and Ce anomalies) from volcanic opals (Ba < 110 ppm, no Eu or Ce anomaly). The Ca content, and to a lesser extent that of Mg, Al, K and Nb, helps to distinguish gem opals from different volcanic environments. The limited range of concentrations for all elements in precious (play-of-color) compared to common opals, indicates that this variety must have very specific, or more restricted, conditions of formation. We tentatively interpreted the presence of impurities in terms of crystallochemistry, even if opal is a poorly crystallized or amorphous material. The main replacement is the substitution of Si⁴⁺ by Al³⁺ and Fe³⁺. The induced charge imbalance is compensated chiefly by Ca²⁺, Mg²⁺, Mn²⁺, Ba²⁺, K⁺, and Na⁺. In terms of origin of color, greater concentrations of iron induce darker colors (from yellow to “chocolate brown”). This element inhibits luminescence for concentrations above 1000 ppm, whereas already a low content in U (≤ 1 ppm) induces a green luminescence.  相似文献   

XEPOS型偏振能量色散X射线荧光光谱仪分析蒙古铁矿石   总被引：5，自引：4，他引：1  

耿刚强  宁国东  王巧玲  丁慧  朱明达  白福全  董海成  牛素琴  王再田 《岩矿测试》2008,27(6):423-426

以熔融玻璃片和粉末压片制样,采用XEPOS型偏振能量色散X射线荧光光谱仪,建立了铁矿石中总铁、氧化钙、氧化镁、二氧化硅、三氧化二铝、硫、磷、铜等组分的快速分析方法。着重讨论硫、磷两元素测定的可行性和Lucas-Tooth、Price数学校正模型的适应性和改善方法的途径。  相似文献   

等离子体质谱法测定玄武岩中微量元素三种样品预处理方法的比较   总被引：3，自引：1，他引：2  

韩江伟  熊小林  朱照宇  吴金花 《岩矿测试》2008,27(5):325-328

在测定玄武岩的微量元素时,为了保证得到的微量元素结果反映源区特征,需经预处理去除玄武岩的孔洞中充填的碳酸盐等物质。选取雷州半岛新生代玄武岩三个样品,每一个样品用三种预处理方法进行预处理,等离子体质谱法测定其中的微量元素。分析结果表明,用稀硝酸浸泡样品,会导致玄武岩中大多数微量元素严重丢失,得到的数据失真;而用稀盐酸浸泡去除碳酸盐的方法基本不改变玄武岩中微量元素的含量。  相似文献   

内蒙古敖包吐萤石矿床的Sr、Nd、Pb同位素地球化学特征   总被引：2，自引：1，他引：1  

许东青  聂凤军  刘妍  张万益  云飞  张天俊  林日亮  吕旭光 《矿床地质》2008,27(5):543-558

敖包吐萤石矿床是内蒙古北部苏莫查干地区单一萤石矿集区中的一个代表性矿床,产于早二叠世大石寨组火山-沉积岩与早白垩世敖包吐花岗岩的接触带上。文章通过分析该矿床岩、矿石的微量元素和稀土元素,揭示出萤石的成矿作用可分为2个阶段,即交代作用和充填作用。交代作用过程中大石寨组的结晶灰岩可能为萤石的形成提供了部分Ca来源,萤石矿石的稀土元素配分模式与海水基本类似,具有Ce负异常;成矿作用后期主要表现为充填作用,形成颗粒粗大的萤石,表现为重稀土元素富集的特征,并随着萤石的沉淀析出,稀土元素总量逐渐下降,反映出成矿流体经历了较长期的演化过程。各地层单元、花岗岩体和萤石矿石的Sr、Nd、Pb同位素研究表明,萤石的放射性同位素组成具有壳、幔源混合的特点,成矿物质来源具有多源性。早白垩世敖包吐花岗岩可能是萤石中F的主要来源,而大石寨组的结晶灰岩则可能提供了Ca。另外,Pb、Nd同位素的极大不均一性,有可能是成矿流体在运移过程中对艾力格庙群放射性组分的选择性吸收的结果。萤石成矿作用与钾玄岩的时空关系暗示了萤石的成矿过程可能是中国东部岩石圈减薄和下地壳的置换地质事件的结果。在构造转型的过程中,燕山中期富碱的酸性花岗岩浆的活动分异出富含F的成矿流体,与幔源流体混合,沿区域重新活化的深大断裂和大石寨组的层间破碎带上升,交代其间的灰岩透镜体,从而形成敖包吐中型萤石矿床。  相似文献   

塔里木盆地塔中1井藻纹层白云岩与竹叶状白云岩成因——基于岩石学、元素与同位素地球化学的厘定   总被引：1，自引：0，他引：1  

陈永权  周新源  赵葵东  杨文静  董晨阳  朱长见 《地质学报》2008,82(6):826-834

塔里木盆地寒武系—奥陶系底部发育了大量的白云岩, 白云岩中赋存丰富的油气资源, 但是由于塔里木盆地白云岩研究基础薄弱,限制了塔里木盆地白云岩型油气藏的勘探。本文选择塔中地区塔中1井下奥陶统藻纹层白云岩与夹层竹叶状白云岩作为对象,应用岩石学与地球化学方法对其成因问题进行了研究。藻纹层白云岩与夹层竹叶状白云岩的宏观构造与微观结构指示其可能形成于高能的潮坪环境;低有序度值（0.6）与塔北地区中寒武统阿瓦塔格组潮坪同沉积白云岩(有序度值0.61)特点一致,指示该白云岩结晶速率较快;同时,高Fe、Mn含量与低U、Mo含量也与氧化环境的潮坪相一致。藻纹层白云岩与夹层竹叶状白云岩δ18O值非常集中, 变化在-7.4‰～-5.8‰;87Sr/86Sr组成变化很小,在0.709015～0.709276之间,与前人报道的晚寒武世－早奥陶世海水同位素特征一致,同时白云岩的稀土元素配分模式也与下奥陶统泥晶灰岩一致,指示了白云岩的沉积/成岩物质来源于蒸发海水;白云岩δ13C值变化从-2.5‰～+1.6‰,并有着随深度增加而升高的变化规律,可能指示了古海洋的碳同位素氧化。藻纹层白云岩与夹层竹叶状白云岩的构造特点具有原生沉积特征,同时白云岩CaO与MgO含量的正相关关系也支持该白云岩原生沉积特点。因此,塔里木盆地塔中1井钻遇的下奥陶统藻纹层白云岩与夹层竹叶状白云岩为潮坪环境下,从蒸发海水中快速沉积形成的。  相似文献   

江西省德兴铜矿矿区重金属元素的环境效应   总被引：6，自引：0，他引：6  

初娜  赵元艺  张光弟  杨慧 《地质学报》2008,82(4):562-576

本文系统研究了德兴铜矿排石场和尾砂库的环境问题,以环境介质（水土植物）中重金属元素含量为研究对象,论述矿区重金属的环境效应。研究结果表明祝家村低品位矿石堆浸场淋滤产生的酸性废水是造成大坞河流域重金属污染的主要来源。大坞河上游水体中Cu元素含量高达14506μg/L,是国家Ⅲ级水标准的14倍之多,Zn元素含量高达2938μg/L,是国家Ⅲ级水标准的2.9倍,同时pH值在3~4范围内;到中下游水体中Cu元素含量减小到几千到几百μg/L,水质有所改善。大坞河沿岸上游和中游土壤重金属含量受河水影响,随着与河岸距离的增加而减小。同时水稻中Pb元素含量是国家粮食标准的2倍。推测4#尾砂库尾砂表层氧化带深度大于80cm;而1#尾砂库库内尾砂中氧化带估计在0~25cm处。推测两个尾砂库产酸能力小于酸中和能力,故坝底水中pH值在7左右,对周围水体影响较小。与4#尾砂库距离近的石墩头村稻田表层土壤中Cu、Mo元素含量较高,远离尾砂库土壤中重金属含量降低。同时4#尾砂库周围土壤中Cd、Pb、Cu元素的吸附态、碳酸盐态比例在20%左右,因而在酸性环境下较容易被植物吸收。1#尾砂库矿建村种植的小白菜中Pb元素含量超过国家蔬菜标准的4倍,Cu、Pb、Zn元素含量严重超过背景值。  相似文献   

Modeling on adsorption–desorption of trace metals to suspended particle matter in the Changjiang Estuary     

Y. Y. Zhang  E. R. Zhang  J. Zhang 《Environmental Geology》2008,53(8):1751-1766

The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary. As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L⁻¹). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural SPM as a simple surfaced molecule.  相似文献   

Evaluation of rock-mass permeability tensor and prediction of tunnel inflows by means of geostructural surveys and finite element seepage analysis   总被引：1，自引：0，他引：1  

N. Coli  G. Pranzini  A. Alfi  V. Boerio 《Engineering Geology》2008,101(3-4):174-184

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Timing of UHP metamorphism in the Hong’an area,western Dabie Mountains,China: evidence from zircon U–Pb age,trace element and Hf isotope composition     

Yuan-Bao Wu  Shan Gao  Hong-Fei Zhang  Sai-Hong Yang  Wen-Fang Jiao  Yong-Sheng Liu  Hong-Lin Yuan 《Contributions to Mineralogy and Petrology》2008,155(1):123-133

The Hong’an area (western Dabie Mountains) is the westernmost terrane in the Qinling-Dabie-Sulu orogen that preserves UHP eclogites. The ages of the UHP metamorphism have not been well constrained, and thus hinder our understanding of the tectonic evolution of this area. LA-ICPMS U–Pb age, trace element and Hf isotope compositions of zircons of a granitic gneiss and an eclogite from the Xinxian UHP unit in the Hong’an area were analyzed to constrain the age of the UHP metamorphism. Most zircons are unzoned or show sector zoning. They have low trace element concentrations, without significant negative Eu anomalies. These metamorphic zircons can be further subdivided into two groups according to their U–Pb ages, and trace element and Lu–Hf isotope compositions. One group with an average age of 239 ± 2 Ma show relatively high and variable HREE contents (527 ≥ Lu_N ≥ 14) and ¹⁷⁶Lu/¹⁷⁷Hf ratios (0.00008–0.000931), indicating their growth prior to a great deal of garnet growth in the late stage of continental subduction. The other group yields an average age of 227 ± 2 Ma, and shows consistent low HREE contents and ¹⁷⁶Lu/¹⁷⁷Hf ratios, suggesting their growth with concurrent garnet crystallization and/or recrystallization. These two groups of age are taken as recording the time of prograde HP to UHP and retrograde UHP–HP stages, respectively. A few cores have high Th/U ratios, high trace element contents, and a clear negative Eu anomaly. These features support a magmatic origin of these zircon cores. The upper intercept ages of 771 ± 86 and 752 ± 70 Ma for the granitic gneiss and eclogite, respectively, indicate that their protoliths probably formed as a bimodal suite in rifting zones in the northern margin of the Yangtze Block. Young Hf model ages (T _DM1) of magmatic cores indicate juvenile (mantle-derived) materials were involved in their protolith formation. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献